石墨化电炉炉阻的研究

提出了一个简明的炉阻计算公式，论述了炉阻实际上是由大量接触电阻构成的立体网络电阻。对电阻料之电阻率的离散性和起始炉阻的离散性作了比较深入的分析。给出了电阻料电阻率，相同装炉参数下炉阻的统计平均值和标准偏差。对炉阻异常，推荐了一种判断的方法。     

流速对投加生物促生剂修复水质效果的影响

为研究水流流速对投加生物促生剂修复水质效果的影响，进行了实验室小试。试验中投加生物促生剂BE10mL／m^3。底泥3000mL，分别考察了水流流速为0、0．050、0．065、0．091m／s时污水中总磷、磷酸盐和总氮的去除情况。试验结果显示，在相同的污泥负荷和BE投加量情况下，流速对污染物去除效果的影响较明显；其中影响最明显的是磷酸盐，去除率高迭99％；得出最佳流速为0．050m／s。     

气力流槽的设计计算

气力流槽是一种常用的固体粉料、粒料的输送设备。它适用范围广,结构简单,制造价格低廉。本文从理论上论述了影响气力输送物料流量的各个因素,为设计和使用设备提供了理论依据。     

Faceting of High-Angle Grain Boundaries in Titanium-Excess BaTiO3

The grain boundaries in BaTiO₃ with excess Ti of 0.5, 0.3, and 0.1 at.% sintered at 1300° or 1250°C have been examined by scanning electron microscopy (SEM), electron backscattered diffraction pattern (EBSP), and transmission electron microscopy (TEM). In the 0.1% Ti-excess specimen, large grains growing abnormally form high-angle grain boundaries when they impinge on each other as verified by EBSP. A large fraction of these grain boundaries are faceted with hill-and-valley shapes. In the 0.5% Ti-excess specimen, large grains growing abnormally are elongated in the directions of their {111} double twins. These grains often form flat grain boundaries parallel to their {111} planes with the fine matrix grains, and the grain-boundary segments between the large impinging grains with high misorientation angles are often also parallel to the {111} planes of one of the grains. These grain boundaries are expected to be singular. Most of the grain boundaries between the randomly oriented fine-matrix grains in the 0.3 at.% Ti-excess specimen are also faceted with hill-and-valley shapes at finer scales when observed under TEM. The facet planes are parallel to {111}, {011}, and {012} planes of one of the grain pairs and are also expected to be singular. These high-angle grain boundaries lying on low index planes of one of the grain pairs are similar to those observed in other oxides and metals.     

二次烧成亚光釉的研制

通过用几种常见的釉用化工原料及废玻纤，经实验、调试，制成具有绢丝光泽的亚光釉并对相关工艺进行了评述。     

基于Pro/TOOLKIT异步模式特征识别方法

对Pro／Engineer（Pro／E）二次开发工具Pro／TOOLKIT（PTC公司为Pro／E软件提供的二次开发工具包）的异步模式进行了研究，充分利用参数化技术，开发了实体模型的特征识别系统。系统可以控制Pro／E的自动启动及关闭，使其在后台运行。通过模型的调用实现实体特征的快速识别提取，为模具估价系统的智能化设计做好了准备。     

酚醛泡沫夹芯板甲醛释放与检测初步探讨

对酚醛泡沫夹芯板中甲醛的来源、释放的影响因素以及控制方法进行了初步探讨。介绍了国内外关于人造板甲醛释放量的相关规定。根据材料的特点及甲醛释放情况,采用40L干燥器法进行了甲醛检测,并进行了讨论。结果表明:与仲裁检测法———1m3气候箱法相比较,该检测方法的结果偏差很小,当取置信水平为0.95时,检测结果的变异系数均小于10%,重现性好。     

尿素合成气的取样技术

介绍了我国尿素合成在线分析的现状及在取样技术上遇到的困难，针对这一难点，研究设计了旋液分离器及成套系统，经实际应用，效果较好。     

Photocatalytic decoloration of water-soluble azo dyes by reduction based on bisulfite-mediated borohydride

Investigation of the photocatalytic decoloration of nine water-soluble anionic azo dyes widely used for the coloration of textiles was conducted in a photoreactor by a selected reduction based on bisulfite-mediated borohydride. The influence of the irradiation power on their decoloration was discussed in this work. The decoloration processes of two typical azo dyes, Reactive Red MS and C.I. Direct Blue 15 were examined with UV–vis measurement and their decoloration kinetics was also investigated. Moreover, identification of benzidine compounds released from the photoreduction of four direct dyestuffs was undertaken. The results indicated that the reduction of the dyes was significantly enhanced under the increasing irradiation. It was found that the overall degradation followed pseudo-first-order kinetics and two distinct stages were observed in the decoloration processes of Reactive Red MS and C.I. Direct Blue 15. The decay rates at first stage were slightly changed, but the decay rates at second stage were significantly affected by the light intensity. In addition, UV–vis spectra showed that the azo linkages in molecule structure of the dyes were destroyed during the decoloration. Finally, dimethoxyl benzidine or benzidine produced from the photoreduction of four direct dyes was identified as the decoloration products through a rapid spectrophotometric method.     

甲基氯硅烷单体合成反应中CuCl催化剂改性研究

针对甲基氯硅烷单体直接合成反应,提出了一种采用甲基三氯硅烷(M1)对CuC l催化剂改性的新方法。由湿法制备的CuC l催化剂表面具有大量的羟基,通过M1改性后,采用红外光谱表征,其表面羟基大幅度减少。采用反应热重的实验方法对CuC l和硅粉共同形成活性中心的反应进行了评价,结果表明改性后的催化剂能够降低形成活性中心的引发温度,为评价单体合成反应找到了一种更为简便的方法。甲基氯硅烷合成反应评价装置上的催化反应结果表明,使用改性后的CuC l催化剂,反应活性提高了大约50%,选择性大约提高了3%,同时S i粉的最大转化率也有很大提高。